The Science of "Water Hardness" General Hardness or GH is the measure of calcium (Ca++) and magnesium ions (Mg++) dissolved in water. Water with a GH will contain a lot of calcium and/or magnesium. This is great if you are keeping African cichlids or other fish that like hard water. While excessive GH is not dangerous to tropical fish, many species come from water with a GH level of 35-ppm to 90-ppm (2-5° dGH). Most aquatic plants also prefer a GH level of 35-ppm to 90-ppm (2-5° dGH). Excess GH also contributes to white scale build-up on the aquarium lid and light fixture. As aquarium water evaporates calcium and magnesium (and other minerals) are left in the water causing GH to rise over time. Lowering GH (softening) has no effect on pH. Carbonate Hardness, also known as KH, refers to the concentration of bicarbonate (HCO3-) and carbonate (CO3--) dissolved in water. KH is important in relation to pH. KH, also known as alkalinity or buffering capacity directly affects the ease of making pH adjustments. In freshwater a high KH level makes lowering the pH very difficult. Each time a pH adjuster is added some of the KH is "neutralized". Each consecutive dose reduces the buffering capacity (KH) of the water. The pH will not go down, however, until the "breakpoint" is reached. When the breakpoint is reached the KH is sufficiently reduced to allow the pH to go down. This is why it may take several doses of aquarium pH adjusters to successfully lower the pH. Adjusting the pH is much easier after the KH has been reduced. Maintaining the pH once adjusted can be difficult with tap water having a high KH level. Every time tap water is added more KH is added to the aquarium. This shifts the water chemistry toward a higher pH level. Additionally, when water evaporates, it leaves all the hardness minerals in the aquarium. Some aquarists use distilled water to replace evaporated water. (Other kinds of bottled water like spring water are usually high in minerals and will increase water hardness.)The best way to manage water hardness levels is the Tap Water Filter. The Tap Water Filter will remove all minerals and pollutants from tap water, permitting easy adjustment of pH and water hardness. The pH of some synthetic marine salts stabilize below or above the recommended 8.2 to 8.4 pH range. Even though the KH is acceptable, the pH may not be right for the aquarium. Water with very low KH may experience wide fluctuations in pH because the buffering capacity is low and small changes make big swings. A high KH level indicates that the pH will be very stable. High KH is almost always associated with a high pH. |